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Five-Color Niv-Mizzet is both one of the hottest decks in Pioneer and my personal favorite deck in the format

Eleven decks ran all three in some configuration (almost 30%)

Being only mono-green, when used as a Commander, Ghalta, Stampede Tyrant severely limits your options on what you can play

And if youre scrying, this card lets you pull cards you put on the bottom of the deck, which gives you more options

Metal Poster Print

Youre ramping very quickly, and youre ramping with lands, so its resistant to sweepers and means you can flip Nissa, Vastwood Seer well ahead of time (turn one Elvish Mystic, turn two Nissas Pilgrimage, turn three Nissas Expedition, turn four Nissa, flip is an example of the fastest way to do it)